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Prepare Brownies as instructed on box using a 9x13" pan.
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Cool completely.
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After they are cool, refrigerate for 1 hour.
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Spread Marshmallow Fluff over the chilled brownies, creating an even layer of marshmallow.
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Return to refrigerator for at least 30 minutes.
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In a large microwave-safe bowl, pour the chocolate chips and the peanut butter.
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Microwave 30 seconds then stir well. If it needs to melt more, microwave in 15 second intervals stirring in between.
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Stir in the Rice Krispies.
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Spread the Rice Krispies layer over the Marshmallow Fluff layer.
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Return to refrigerator for at least another hour before cutting.
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Store in the refrigerator in an air-tight container.